Professor John Winfield, Glasgow University, UK From the Back Cover:Ĭatherine E. One of the most important features (and one that recommended the book to us as a text) is that topics are presented in a straightforward manner, making them accessible to the less able students.” It is pleasing that the authors continue to provide a broad coverage of chemistry throughout the Periodic Table while maintaining a reasonable size of book. “Undoubtedly, the new colour format makes the book seem more attractive to the reader I noted that the descriptive chemistry has been updated also. I thought that the section on Group Theory and symmetry is much better handled in the 2nd edition.” thought that the addition of colour was a major improvement relative to the 1st edition. Clearly, students may prefer the more colorful 2nd edition, and so will their teachers for pedagogical reasons.” The book is also a very good comprehensive text for chemists in general, PhD students and researchers. It was the case of the 1st edition and it remains so for the 2nd edition. “ Housecroft-Sharpe has been the far most superior contemporary inorganic chemistry textbook there is. Professor Nikolaus Korber, University of Regensburg, Germany " I've had one of my students take a look at the book and I virtually had to tear it from his hands in order to get it back!" Markku Sundberg, Helsinki University, Finland The problems related with each chapter are good and the suggestions for further reading are highly relevant.” Furthermore, it is well and logically presented. The book contains all the information needed. In the modern IUPAC nomenclature, the alkali metals comprise the group 1 elements, excluding hydrogen (H), which is only nominally considered a group 1 element.“ To put it short, this is THE BOOK, that I would like to use in Inorganic Chemistry. Because of their high reactivity, they must be stored under oil to prevent reaction with air, and are found naturally only in salts and never as the free element. They can all be cut easily with a knife due to their softness, exposing a shiny surface that tarnishes rapidly in air due to oxidation by atmospheric moisture and oxygen. The alkali metals have very similar properties: they are all shiny, soft, highly reactive metals at standard temperature and pressure and readily lose their outermost electron to form cations with charge +1. The alkali metals provide the best example of group trends in properties in the periodic table, with elements exhibiting well-characterized homologous behaviour. The alkali metals have their outermost electron in an s-orbital and this electronic configuration results in their characteristic properties. The structures of the metals can be summarised by the table below which shows that most metals crystallise in roughly equal amounts of bcc, hcp and ccp lattices.Ĭrystal structure of metallic elements in the periodic table Mercury, caesium and gallium have melting points below 30 ☌ whereas all the other metals have sufficiently high melting points to be solids at "room temperature". For a given period, the melting points reach a maximum at around Group 6 and then fall with increasing atomic number. In the alkali metals (Group 1) and alkaline earth metals (Group 2) the melting point decreases as atomic number increases, but in transition metal groups with incomplete d-orbital subshells, the heavier elements have higher melting points. The transition metals have generally higher melting points than the others. Melting points are chosen as a simple measure of the stability or strength of the metallic lattice. cubic close packed (face centered cubic) has every third layer directly above/below each other, A,B,C,A,B,C.hexagonal close packing has alternate layers positioned directly above/below each other, A,B,A,B.It can be envisaged that for a regular buildup of layers: If the close packed structures are considered as being built of layers of spheres then the difference between hexagonal close packing and cubic close packed is how each layer is positioned relative to others. For closest packing, every atom has 12 equidistant nearest neighbours, and therefore a coordination number of 12. A simple model for both of these is to assume that the metal atoms are spherical and are packed together in the most efficient way (close packing or closest packing). cubic close packed (face centred cubic) and hexagonal close packed structures. Many metals adopt close packed structures i.e. This basic repeating unit is called a unit cell. \)Ĭrystalline solids consist of repeating patterns of its components in three dimensions (a crystal lattice) and can be represented by drawing the structure of the smallest identical units that, when stacked together, form the crystal.
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These awards serve as a testament to the winery's commitment to producing wines that captivate and delight wine enthusiasts. The oval head is concave, reminiscent of a satellite dish, with a gorgeous. Space Age Rosé has garnered accolades and recognition for its outstanding quality and unique style. DATE: Space Age, c.1960 Striking vintage ring dating from the 1960s Space Age. Their dedication to quality and attention to detail shines through in every bottle. With a deep respect for tradition and a desire to push boundaries, the winemaker crafts wines that are both approachable and thought-provoking. is helmed by a passionate and innovative winemaker who brings a modern approach to winemaking. Grenache ros from vineyards in Paso Robles and Monterey County of the Central Coast, California. The result is a beautifully balanced Rosé that showcases the best qualities of the grapes. Space Age Ros - Rocket to Refreshment By: Jon Thorsen Published: ApLast Updated: A hypersonic trip to delicious, the Space Age Grenache Ros from Grounded Wine Company. Gentle pressing and cool fermentation techniques are employed to preserve the wine's freshness and natural acidity. The grapes are carefully harvested at optimal ripeness to ensure the vibrant fruit flavors are captured. Follow Josh Phelps on Instagram and Twitter. Space Age Rosé involves a delicate balance of science and artistry. Space Age Ros Spritz is sold in individual 250 mL cans or in 4-packs at retailers across the country for 3.49 per can or for 13.99 per 4-pack. Winemaking Process: The winemaking process for Grounded Wine Co. Its lively acidity and crisp finish leave you longing for another sip. Grenache is the French (and most internationally recognized) name for the grape, but it has a number of synonyms. Brad Pitt, Sean Bean, Saffron Burrows, Eric Bana, Orlando Bloom, Rose. Bursting with juicy red berries, ripe watermelon, and a hint of citrus, it offers a refreshing and zesty profile that is perfect for warm days and outdoor gatherings. Space Age (TV Mini Series 1992 ) - Movies, TV, Celebs, and more. Taste Profile: Prepare your taste buds for an explosion of flavors in this Rosé. All compositions by Sun Ra Enterplanetary Koncepts (BMI) except: Back in Your Own Back Yard by Jolson-Rose-Dreyer (. The specific grape varietals used may vary, but they are chosen to create a harmonious and expressive Rosé that captures the essence of the region. The Low-yielding Grenache vines are the basis for. Space Age Rosé is made from a blend of 93% Grenache and a 7% Cinsault sourced from the Central Coast region, across Monterey, Santa Barbara and Edna Valley. The grapes used for Space Age Paso Robles Rose came from three select parcels in the Paso Robles appellation. Grape Varietals & Region: Grounded Wine Co. Crafted with care and a touch of whimsy, this Rosé is sure to delight wine lovers with its vibrant character and out-of-this-world experience. Space Age Rosé Central Coast 2020 is a captivating and refreshing wine that takes you on a cosmic journey of flavor. I will do my best to pack it carefully and minimize any creasing to the fabric.Grounded Wine Co. During the ignition sequence, the rocket rose about three feet above the platform, shook briefly, and disintegrated in flames. Therefore it will likely need steaming or to hang out once received. Will fit a range of sizes but is probably best on someone with ample shoulders and height.īust 38" (measurement taken pit to pit, laying flat and doubled)Ī note on shipping: This vest will need to be folded in order to fit into a box that isn't huge and costly to ship. A faint gray area on the front right shoulder perhaps where a darker garment rubbed against it while hanging. The neon print ruffly collar micro mini tunic not included, sold separately.Ĭondition: Noticeable small rusty looking spot in the front. This listing is for the white beaded tunic only. Space Age Rosé & Rosé Spritz Space Age On the night of July 20th, 1969, we all stared at the moon and listened to the radio chatter of the Apollo 11 astronauts. Pearl quilted fabric embellished with large paisley design in black sequins.Ĭloses at the neck and otherwise worn open. Makes me think of something Moira Rose of Schitt's Creek would wear. Space age tunic vest by Mary McFadden, something I haven't seen before. Which means, whilst still in the Plugins pane of the Deluge Preferences, select the Install Plugin button & then navigate with the file requester to where you have the eMule ipfilter.dat & then type the path to it in the location field (it opens up once you start navigating in the file requester), using the following format:Īfter that it may be a good idea to restart Deluge to initialise the block list. The Deluge blocklist plugin can be found at. Here is the installation path for the unzipped contents: Here is the installation path for the unzipped contents after unzipping the file & calling it ipfilter.dat : īlock List installation The Quick Way For Deluge It has also been tested in qbittorrent.Īnother option for a block list can be found at. The added bonus is that you can use eMule block list in other torrent clients. One source for a block list is the one that eMule uses. If you want to use a Block list with Deluge, open the Preferences panel, where you will find a Plugins option, a long way down the list on the left hand side select it, then in the Plugins pane select (tick) the built in Block list plugin. The most time consuming problem was finding a block list for Deluge to import. Often you'll see different kinds of insults on discussion forumsįrom people who just want to ridicule other p2p users that are Results in bad and incorrect information being spread with no Of technical knowledge mixed with extremely poor research simply While in some cases the false information has been outrightįabricated lies intended to do damage, it also seems that a lack Added IP filter dialog for basic editing and viewing IP filters (accessible via Tool menu). More tolerance in eMule IP filter format files (level and description is now optional). Some of this false information may be part of a deliberateĬampaign to discredit the blocklists and their maintainers, orĪn attempt to trick people into lowering their defences byĬonvincing people they are either more at risk or wasting their More safety in determining format of IP filter files (support for eMule IP filter and PeerGuardian file formats). This has led to the development of common misconceptions about Information posted around the net regarding the use ofīlocklists as a unreliable form of protection against a wide Over the years we have heard all kinds of false and incorrect This is a small part of the start of his article, just to get you going:īlocklists block billions of innocent people Unfortunately, the full article is no longer available. This is a highly informative article written by a professional in the IT Security industry. 1 Firstly, are Block Lists worth the trouble?įirstly, are Block Lists worth the trouble?. 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It is a complete suite that is specially designed for real-time video editing, previewing all the changes made by the user and doesn’t require any rendering or exporting. It is a comprehensive suite which provides the users with a wide range of powerful tools and options pre-included with a massive stock library for different projects with videos, images, music tracks and templates. It enables users to easily use advanced effects to create eye-catching videos like filters, animations, transitions, behaviors, text, audio, and so on. The application has advanced ability to not only record and edit but also capture memories, weddings, romance, travel, sports, pets, cooking and more. Through the application, users can easily edit any video they want without facing any limitation or video format capability issues. TunesKit AceMovi 2021 is an intuitive application that comes loaded with amazing features and tools that lets users to simply record your screen or import their media, drag and drop text, music, transitions, and more effects, and then export. You can also download MAGIX Movie Edit Pro 2020 Free Download. It also supports modern operating systems which also includes the MacOS, giving access to Apple users. This application lets users work with different video editing tools in which users can edit with transitions, filters, animations, music, text, templates and more all in a single application. TunesKit AceMovi 2021 is an application which can be used as a powerful and advanced video editing tool through which users can easily enhance their videos with high-quality effects and filters. It is a full offline installer standalone setup of TunesKit AceMovi Free Download for 32/64 Bit. TunesKit AceMovi 2021 Free Download Latest Version for Windows. I permanently deleted my Spotify account but my data is not completely removed from Spotify yet. The company can use the retained data to resolve disputes related to your account or any sort of situation that requires fraud and grievance redressals. What type of data will Spotify have access to after I permanently delete my account?Įven if you delete your Spotify account permanently, Spotify will still retain some of your data for tax, accounting, and regulation purposes. To read more about the save visit the Spotify Privacy Policy page To read in detail about the type of data that Spotify collects about you, read this article right away. After that, Spotify continues to collect data like your playlists, search queries, your followers and following, and much more. During signup, you share your email address, phone number, and geolocation with Spotify. Spotify collects a plethora of information about you. What type of data do we share with Spotify? It will open a drop-down menu, where you need to click on “ Account.” Then, click on your username in the top right corner. First, log into your Spotify account on your preferred browser. Here, we are using the Chrome browser on a Windows PC to show the steps to delete a Spotify account.ġ. So, if you have the Spotify app installed on your Windows PC, Mac, or smartphone, it will redirect you to Spotify’s support website. Before that, remember you can only delete your Spotify account via the web. You can delete your Spotify account permanently by following the steps outlined below. Permanently Delete Your Spotify Account on the Web/ Desktop The streaming giant will also be able to use the data that is necessary to resolve any disputes related to your account or any sort of situation that requires fraud and grievance redressals. However, Spotify will still be able to retain some of your information for tax, accounting, and regulation purposes. Hence, from your end, you will not have any form of access to your Spotify account and data. You will also stop receiving updates and emails from your Spotify account. Your account will not appear on search, and it will not be visible to anyone anymore.Ĥ. We’ve provided access to help in a way that is visible and direct.3. We’ve provided evidence and communicated progress. We’ve informed the user of what’s happening and why. And just tell me what you did when you went away for ages. “Tell me why the issue was caused in the first place. Offer users visible and direct access to help, with transparent communication in both human and automated channels. Ok, enough principle preambling - here are the principles themselves! Rather they’re a peek into our personal crystal ball and a glimpse of what’s to come. That means the illustrations you see below don’t reflect what’s on the Support site now. Note that these principles are newly established, so in time they’ll shape how we think about the Support site. You’ll notice that not every illustration ticks every box on its corresponding checklist, but that’s okay! They’re meant to be a reminder of our goals, and every checklist item may not apply in all situations. There’s also a handy checklist that shows how we evaluate whether we’re delivering on the principle. We came up with these principles over the past few months by 1) talking with users to understand their needs, and 2) adopting familiar design patterns that we’ve seen work well at Spotify.īelow, we explain each principle and illustrate how it applies to an experience on our Support site. So how do we strive to get the help moments right? In lots of little ways, of course, but moreover by starting to follow some foundational principles that we feel are particularly suited to designing for our Support experience. And it’s our job to ensure that our service truly serves the needs of the people! Beyond traditional product and brand design, we've got a whole bunch of services at Spotify that need design magic. We work on the support experience at Spotify - specifically the resources that help users help themselves. Oh and allow us to introduce ourselves! We’re a design and research duo from the CSAT team (it stands for “Customer Support Systems And Technology”). You won’t be surprised that we’re always striving for the latter :-) A bad help moment makes a frustrating experience even worse, while getting the help moment right can build lasting trust between a company and a human. Pieces with adjustable shoulder straps allow you to customize the fit so that it perfectly hugs your body. AirSlim® Open Bust Seamless Smoothing Body Shaper.A piece of high-quality shapewear that is up to solve the "back-fat task". Yes, they're comparable to one-piece swimsuits, only more elastic and compressive. The compression and elasticity also help spread extra fat or skin evenly, creating a more balanced look. Being a single, cohesive piece means that there are no cracks, gaps, or holes for the fat to spill out from (think tight denim jeans causing a muffin top). These types of shapewear are great for back fat due to their seamless, uninterrupted silhouette. They can end in either shorts that go down to your thigh (or even mid-thigh), briefs, or thongs. They're often styled as bodysuits or rompers with a deep, wide cut at the front for your breasts. The bra-less body shaper allows you to wear your favourite bras beneath them (a great way to avoid unnecessary layering and keep a familiar, comfortable fit). Here are the three shaper styles capable of controlling back fat, and take care of that extra skin, if you need it to. All while rocking your actual size and loving how you look in it. And they can do it in a way that looks natural and seamless. At times like these, a little shaping and tucking in the lower back and torso can be a godsend.Ĭertain shaper garments are specifically designed to target back fat-even if they don't explicitly say so. Keep rocking it.īut, we all have moments where we'd rather flatten, not flaunt, the extra back flab. So if you're comfortable with your body, belly rolls, love handles, and all, more power to you. We're here to say that it's 100% normal and 100% okay when that happens because we can't all be picture-perfect IG models (who we know for a fact still feel insecure and photoshop their pictures). What's worse is that ill-fitting bras (that create a bra bulge), too-tight tops (with "false" adjustable straps), and size-too-small jeans can accentuate our belly and back bulge, and hide our natural waist. Unfortunately, that's not the case for 99% of us. In an even better world, we wouldn't have to feel self-conscious about fat. In an ideal world, excess fat would be evenly distributed all over the body with a size chart that helps us instead of making us super conscious that we added one more number to it. Meaning, we're more than familiar with terms like muffin top, side boob, and-of course- love handles. As women, we're constantly exposed to body-conscious content on social media. Once your bookkeeper receives all the necessary documentation, they’ll typically complete your cleanup within 30 days. The services provided during the first month are as follows, as applicable: update bookkeeping based on information you provide connect bank and credit cards categorize and update transactions up until the last tax-filing date reconcile bank and credit card accounts with past statements, as provided by you reconcile remaining balance sheet accounts and run a summary report of work completed, balance sheet, and profit loss statement of YTD for cleanup period(s).Ī Live Bookkeeper cannot begin cleaning up your past books until they receive the required supporting documentation, which your bookkeeper will request from you after your first meeting. QuickBooks Live Monthly Bookkeeping services : After signup, a Live Bookkeeper provides cleanup services that start from the date of your last business tax return or business incorporation date (if more recent) through the end of the calendar month before first sign-up to Live Bookkeeping. If your monthly average is $50,001 or more, the monthly price for QuickBooks Live is $400. If your monthly average is $10,001-50,000, the monthly price for QuickBooks Live is $300. If your monthly average is $0-10,000 per month, the monthly price for QuickBooks Live is $200. Your business’s average monthly expenses and associated subscription pricing may be reassessed at Intuit’s sole discretion. After the first month, you’ll be charged monthly at the then-current monthly fee based on your average monthly expenses over the previous 3 months, unless you cancel. Following a 30 day period after signup, the ongoing Live Bookkeeping service is available in 3 different pricing tiers, depending on your company’s average monthly expenses over a period of 3 consecutive months. Cleanup fee is customized based on signup month, tax filing status, and business start date. QuickBooks Live Cleanup is required for Live Monthly Bookkeeping. QuickBooks Live Monthly Bookkeeping pricing tiers : Live Bookkeeping is available to QuickBooks Online subscribers and is sold separately. Live Bookkeepers aren’t responsible for errors resulting from incorrect information that you provide, or if you re-open the books by overriding closure after a Live Bookkeeper completes the month-end closure. You’ll need to provide QuickBooks with a receipt for the transaction in question, correspondence from your outside tax accountant, or a document stating the balance of the account if an account balance is in question. If you invoke the guarantee, QuickBooks will conduct an evaluation of the Live Bookkeeper’s work. An “error” is: a) a transaction that has been incorrectly categorized to the wrong account b) an account balance in QuickBooks that doesn’t match the actual account balance or c) improper transactions which can’t be supported by documentation (including client responses and client meeting notes). If your Live Bookkeeper makes an error that requires you to re-open your books for any month, we’ll correct the error in your books for the month that the error occurred at no additional charge.Įligible errors include only those made by a Live Bookkeeper. At your request, QuickBooks will conduct a full evaluation of your bookkeeper’s work. However, using this ability to block enemies in choke points, will give your team the chance to snag 2 bounty runes, or even get first blood.īased on the demonstrations displayed above, Earthshaker has the potential to completely block off enemy heroes from getting access to the runes. At level 1, Fissure stuns for a mediocre 1 second and deals a respectable 110 damage. Level 1 presenceĪs stated earlier, Earthshaker has the potential to have an insane impact in the first few minutes of any game thanks to his Fissure ability. But for the super secret strategies, and ways to take this hero to an all new level, continue reading the guide. Some quick math for you, if you hit 5 enemy heroes, then Echo Slam will deal up to 1,700 magical damage!Īnd with that, anyone reading this baseline description will be equipped to confidently queue up for a ranked game and first picking this hero. Echo Slam does have a base damage of 100, but for every hero you hit in the AoE, the damage goes up by up to 320, and for every creep, up to 160. Echo slam affects all enemies in a 600 AoE, and deals more damage, the more enemies you hit in the AoE, making the ability able to reach unthinkable damage numbers. Echo SlamĮarthshakers ultimate, and by far his coolest ability. This makes it synergize very well with Enchant Totem, since that ability will have a stun as well! Aftershock is what makes this hero have insane crowd control, and allows him to chainstun all enemies in a 300 AoE radius around him for insane durations. Aftershock will stun enemies for up to 1.5 seconds and deal up to 150 magical damage every time he casts a spell. One of Earthshakers simplest and most straightforward abilities. Enchant Totem, however, is nothing without his third ability. This ability is also on a very short 5-second cooldown, allowing him to use it to farm efficiently, and be more active in team fights. Using Enchant Totem, will quadruple your attack damage at level 4, allowing you to trade with enemies, or just finish them off. Enchant TotemĮnchant Totem is Earthshakers bread and butter since this spell gives him the ability to achieve a wide variety of tasks. The main utility that Fissure provides, is that it creates a barrier that enemies cannot walk over, effectively trapping an enemy if used correctly. However, as stuns go, this is a fairly mediocre stun duration. Using this spell will stun enemies for a respectable 1.75 seconds at a 1400 range from your hero in a straight line. To some, this is Earthshakers signature ability, and its easy to see why. This guide will help you to get a brief overview and understanding of his abilities, and then give a few tips and tricks to take the hero to the next level. It is also widely regarded that Earthshaker has the potential to make the highest impact in the first few seconds in the game, all the way to the last. This is because Earthshaker has the potential to bring in top tier crowd control from level 1. If a team lacks lockdown or initiation, then Earthshaker is a good pick to have in your arsenal. Beginners playing this hero will struggle to make the best use out of his abilities, but seasoned veterans like Yapzor, have mastered his many intricacies. What’s so special about Earthshaker?Įarthshaker has a lot to offer to your team in terms of damage, crowd control, and mobility. Here’s an in-depth Earthshaker guide that you can follow. Although he is pretty simple to execute, his abilities also have a skill ceiling higher than Drows Winrate in 7.21d. The inevitable addition of the Earthshaker Arcana is sure to invite players to try out the hero. We showed up at 6 and two other reservations were waiting. So the evening started with a 6pm reservation for two. If you are lucky enough to be driving by, stop and treat yourself. Lastly, I have a gluten intolerance and the staff has bent over backward to make every dish I've ordered gluten-free. Parking can sometimes be frustrating and like everywhere these days the wait staff is stretched thin so at peak times be patient and you'll be rewarded with a great meal. It's no surprise that this place is popular, so call ahead and reserve a table whenever you can. My go-to is the Otter, beer-battered haddock on a roll. The chicken marsala is the best I've had anywhere. The quality bar isn't that high in NH and that's exactly why it's so surprising to find such consistent high-quality delicious food in a small town setting. I've grown up in NH and eaten at many small town resteraunts that provide a passable meal but nothing great. We've eaten on the deck overlooking the lake, in the elegant main restaurant, and when it's just the two of us, in. Since moving to the town a few months ago my wife and I have frequented this establishment.
You May Also Like Java for Mobile App DevelopmentĢ) Cleanup: After scanning your system, Buho will automatically delete all of the junk files found on your hard drive. This includes files that have been left behind by applications like Microsoft Office, Adobe Reader and VLC Player. The program automatically finds the most effective way to clean up your Mac, so you don’t have to worry about it.ġ) Scan: BuhoCleaner will scan your entire system and identify all of the junk files on your hard drive. BuhoCleaner is designed to help you clean up your Mac, remove junk files and keep it running smoothly. So what makes it so good? How does BuhoCleaner Help?īuhoCleaner is a popular Mac cleaning tool that has been around for a while. It has good ratings on the app store as well as on other review sites such as CNET and. It is easy to use and does a great job keeping your Mac running fast and smoothly.īuhoCleaner is one of the most popular Mac Cleaners available today and has been around for quite some time. The best one that I have found is BuhoCleaner. Some of these applications are free while others cost money. As with any computer, there are several applications that can be used to improve the performance of your Mac. Macs are great devices, but they can be hard to maintain.
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